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As a newly Qualified ca, which could be a best platform to wealth maximisation...,
Both are very lucrative options.
Maybe, you can start with employment and side by side start your practice as well. And once you have sufficient no. of clients, maybe you can leave your job and enter into practice full time.
And this is what most of the CA's do i.e. they start with employment and start practice part time and once they have some clients, then they enter into practice full time.